SN/T 5262-2020 in English
VALIDDetermination of individual aromatic and total aromatics in imported mixed aromatics-Didimensional gas chromatography
- Issued on:2020-08-27
- Implemented on:2021-03-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$214.00
Introduction
Technical background and scope of application of the standard
This standard aims at the quality control requirements of key components such as benzene and toluene in imported mixed aromatics, and adopts two-dimensional gas chromatography technology to solve the technical problem that traditional methods cannot separate meta-xylene and para-xylene. It is applicable to the detection scenario of 10%-100% total aromatic content.
Core method principle
| Analysis phase | Valve switching time | Detection target | Chromatographic column combination |
|---|---|---|---|
| First analysis | 0.8min on, 14.5min off | Benzene, toluene | TCEP polar pre-column + methyl silicone analytical column |
| Second analysis | 4.3min on, 22min off | C8-C9+aromatics | Same as the first analysis column system |
Typical case: In the detection of a batch of imported mixed aromatics, the valve switching time was optimized (±0.1min) to increase the separation degree of meta-xylene/para-xylene from 1.2 to 1.8, meeting the quantitative requirements.
Key instrument configuration requirements
- Gas chromatograph: Must be equipped with a ten-port valve switching system with a dead volume of <5μL
- Chromatographic column: Polar pre-column requires 20% TCEP stationary phase, non-polar column film thickness requires 0.5μm
- Detector: FID detector temperature should be stable at 300±1℃
Key points of quality control
| Parameters | Requirements | Verification method |
|---|---|---|
| Standard curve R² | ≥0.990 | 5-point linearity verification |
| Repeatability (r) | ≤1% relative value | 6 parallel determinations |
| Sample storage | 0-5℃ protected from light | Temperature record verification |
Implementation suggestions
- Establish a valve switching time calibration procedure. It is recommended to use xylene mixed standard sample for weekly verification
- When quantifying C9+ aromatics, it is recommended to use 1,2,4-trimethylbenzene as the representative component
- Density conversion should adopt the SH/T 0604 method to measure the sample density

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