GB/T 33351.1-2016 in English
VALIDDetermination of arsenic, beryllium, antimony in electrical and electronic products--Part 1: Inductively coupled plasma mass spectrometry
- Issued on:2016-12-13
- Implemented on:2017-07-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$156.00
《GB/T 33351.1-2016电子电气产品中砷、铍、锑的测定 第1部分:电感耦合等离子体质谱法》由TC297(全国电工电子产品与系统的环境标准化技术委员会)归口,TC297SC3(全国电工电子产品与系统的环境标准化技术委员会有害物质检测方法分会)执行,主管部门为国家标准化管理委员会。
Introduction
GB/T 33351.1-2016 Standard Overview
GB/T 33351.1-2016 "Determination of Arsenic, Beryllium and Antimony in Electrical and Electronic Products Part 1: Inductively Coupled Plasma Mass Spectrometry" is an important national standard for the detection of toxic elements in electrical and electronic products in China. This standard specifies the method of quantitative analysis of arsenic, beryllium and antimony using inductively coupled plasma mass spectrometry (ICP-MS), which is applicable to a variety of sample types such as polymers, metals, ceramics and glass.
Technical Background and Standard Formulation
As the problem of heavy metal pollution in electronic products becomes increasingly prominent, the international community has put forward higher requirements for the detection of toxic elements. This standard is based on ICP-MS technology, combined with pre-treatment methods such as microwave digestion and acid digestion, to ensure the accuracy and reliability of the test results.
During the formulation of the standard, reference was made to the IEC62321 series of international standards, and optimization and adjustments were made in light of China's national conditions to meet the actual needs of domestic electronic and electrical product testing.
Comparative Analysis of Standard Frameworks
| Dimensions | Scope of Application | Reference Documents | Detection Methods |
|---|---|---|---|
| Sample Type | Polymer, Metal, Ceramic, Glass | GB/T6682, IEC62321-2, IEC62321-5 | ICP-MS |
| Detection Elements | Arsenic, Beryllium, Antimony | - | External Standard Method, Internal Standard Elements: Germanium, Lithium, Tantalum |
| Sensitivity | Detection limit: 0.8 mg/kg (arsenic), 0.4 mg/kg (beryllium), 1.4 mg/kg (antimony) | - | Based on the high sensitivity of ICP-MS |
Practical application case analysis
Case 1:Detection of arsenic in a certain electronic product
After mechanical pretreatment, a certain brand of smartphone was pre-treated by microwave digestion. The results showed that the arsenic content in the product was 0.3 mg/kg, which met the national standard requirements.
Case 2:Detection of beryllium in metal solder
The solder sample was digested with a mixed acid of nitric acid and hydrogen peroxide, and the test results showed that the beryllium content was 0.2 mg/kg, which was lower than the standard limit.
Implementation suggestions and precautions
1. Instrument calibration: Ensure that the ICP-MS instrument is calibrated regularly to meet the sensitivity, background and stability requirements.
2. Sample processing: Select the appropriate digestion method (microwave digestion or acid digestion) according to the sample type to avoid introducing interference factors.
3. Internal standard optimization: Rationally configure the concentration of internal standard elements to ensure the linear relationship and accuracy of the calibration curve.
4. Data processing: Strictly calculate the sample content according to the formula, retain three decimal places, and keep good experimental records.

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