GB/T 4333.2-2023 in English
VALIDFerrosilicon—Determination of phosphorus content—Bismuth phosphomolybdate blue spectrophotometric method
- Issued on:2023-09-07
- Implemented on:2024-04-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$156.00
《GB/T 4333.2-2023硅铁 磷含量的测定 铋磷钼蓝分光光度法》由TC318(全国生铁及铁合金标准化技术委员会)归口,TC318SC1(全国生铁及铁合金标准化技术委员会化学分析分会)执行,主管部门为中国钢铁工业协会。
Introduction
1. Standard Overview
GB/T4333.2-2023 standard is used to determine the phosphorus content in ferrosilicon using the bismuth phosphomolybdenum blue spectrophotometric method. This method is suitable for the determination of phosphorus content within the range of $0.010\%\sim0.060\%$ by mass fraction.
2. Comparison of standard frameworks
| Standard version | Main changes | Scope of application |
|---|---|---|
| GB/T4333.2—1988 | Basic structure and method | $0.010\%\sim0.060\% |
| GB/T4333.2—2023 | Add stepwise dilution method, improve instrument requirements and sample preparation process | Keep consistent |
3. Implementation suggestions
3.1 Precautions for reagent preparation
When preparing the phosphorus standard solution, ensure that the concentration and dilution ratio are precisely controlled. It is recommended to use a volume flask and strictly follow the standard operation to ensure measurement accuracy.
3.2 Importance of instrument calibration
The wavelength setting of the spectrophotometer needs to be accurately adjusted to $690~\mathrm{nm}$ and calibrated regularly to ensure the accuracy of the absorbance readings. At the same time, the cleanliness of the cuvette directly affects the results, and it is recommended to use a special cleaning agent.
3.3 Data analysis and processing
When calculating the phosphorus content, special attention should be paid to the units and significant figures of the variables in the formula. The results are rounded to two significant figures, and quality control is carried out in combination with the precision data (repeatability limit $r$ and reproducibility limit $R$).

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