GB/T 4702.15-2016 in English
VALIDChromium metal―Determination of lead,tin,bismuth,antimony and arsenic content―Inductively coupled plasma mass spectrometric method
- Issued on:2016-12-13
- Implemented on:2017-09-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$156.00
《GB/T 4702.15-2016金属铬 铅、锡、铋、锑、砷含量的测定 等离子体质谱法》由TC318(全国生铁及铁合金标准化技术委员会)归口,主管部门为中国钢铁工业协会。
Introduction
1. Background and purpose of the standard
GB/T 4702.15-2016 is the 15th part of the series of standards for chemical analysis of metallic chromium, which is specifically used to determine the content of lead, tin, bismuth, antimony and arsenic in metallic chromium. With the increasing demand for high-purity metals in industrial development, the importance of accurately detecting impurity elements has become increasingly prominent. This standard adopts advanced inductively coupled plasma mass spectrometry (ICP-MS), which has the characteristics of high sensitivity and low detection limit.
2. Comparison of standard frameworks
| Standard number | Applicable elements | Determination method | Release date | Scope of application |
|---|---|---|---|---|
| GB/T 4702.1 | Chromium content | Ammonium ferrous sulfate titration method | 2016 | Determination of chromium in metallic chromium |
| GB/T 4702.6 | Iron, aluminum, silicon and copper content | Inductively coupled plasma atomic emission spectrometry | 2016 | Determination of multiple elements in metallic chromium |
| GB/T 4702.15 | Content of lead, tin, bismuth, antimony and arsenic | Inductively coupled plasma mass spectrometry | 2016 | Determination of trace elements in metallic chromium |
3. Implementation Suggestions
Case Analysis: A metallic chromium manufacturer used this standard method and successfully reduced the arsenic content from 0.0015% to 0.0008%, meeting export requirements. The following are key recommendations for implementation:
- Instrument calibration:Regularly calibrate the ICP-MS instrument to ensure the accuracy of the mass calibration solution (containing beryllium, cerium, iron, etc.).
- Reagent purity:All reagents must be of high purity to avoid the introduction of interfering elements. The resistivity of ultrapure water should be no less than 18MΩ/cm.
- Sample preparation:Sampling must be carried out strictly in accordance with GB/T 4010, the sample particle size must pass through a 1.68mm sieve, and be evenly mixed.
- Blank test:Perform at least one blank test for each batch of analysis to ensure that there is no pollution to the reagents and the environment.

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