GB/T 12686-2017 in English
VALIDGlyphosate acid technical material
- Issued on:2017-12-29
- Implemented on:2018-07-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$204.00
《GB/T 12686-2017草甘膦原药》由TC133(全国农药标准化技术委员会)归口,主管部门为农业农村部。
Introduction
1. Overview of the standard and revision background
GB/T 12686-2017 "Glyphosate Technical Material" was issued in 2017, replacing the previous GB/T 12686-2004 version. The standard mainly stipulates the technical requirements, test methods, signs, labels, packaging, storage and transportation, and acceptance period of glyphosate technical materials.
Compared with the old version, the main technical changes of the new version of the standard include:
- The upper limit of formaldehyde mass fraction is revised from no more than $0.8~\mathrm{g/kg}$ to no more than $1.2~\mathrm{g/kg}$
- The analysis method of nitroso glyphosate is changed from strong anion exchange method to reversed phase liquid chromatography after derivatization reaction
These changes reflect the improvement of product quality requirements and the progress of analytical technology.
2. Comparison table of standard frameworks
| Standard version | Upper limit of formaldehyde mass fraction | Analysis method of nitrosoglyphosate | Scope of application |
|---|---|---|---|
| GB/T 12686-2004 | $0.8~\mathrm{g/kg}$ | Strong anion exchange method | Glyphosate technical and its impurities |
| GB/T 12686-2017 | $1.2~\mathrm{g/kg}$ | Derivatization reaction reversed phase liquid chromatography | Glyphosate technical and its production impurities |
3. Interpretation of technical indicators
According to Table 1, the technical indicators of glyphosate technical include:
Glyphosate mass fraction: 95.0%Formaldehyde mass fraction: 1.2 g/kg
Nitrosoglyphosate mass fraction: 1.0 mg/kg
Sodium hydroxide insoluble matter: 0.2 g/kg
4. Practical application case analysis
A pesticide manufacturer produced glyphosate technical in accordance with GB/T 12686-2017 and found that the formaldehyde content exceeded the standard. By adjusting the production process and raw material ratio, the formaldehyde mass fraction was eventually reduced from $1.5~\mathrm{g/kg}$ to $1.2~\mathrm{g/kg}$, which meets the standard requirements.
5. Implementation suggestions
- High performance liquid chromatograph and spectrophotometer are key instruments for detecting glyphosate technical and need to be calibrated regularly.
- During the production process, it is recommended to measure the mass fraction of nitrosoglyphosate and the content of sodium hydroxide insoluble matter at least once a quarter.
- Enterprises should strengthen employee training to ensure that they are proficient in the test methods and safety precautions in the standard.

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