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chromium content blast furnace method sintering-blast furnace metallurgy method sintering-blast furnace metallurgy method roasting disposal method method using boiler steel structures specification semi-scissor grab non-metallic pipe material quality acceptance specification part
GB/T 39300-2020 in English

GB/T 39300-2020 in English

VALID

Treatment and disposal method for chromium-containing electroplating sludge

  • Issued on:2020-11-19
  • Implemented on:2021-10-01
  • File Format:PDF
  • Delivery:Via email within 1~3 business days
Price(USD): $130.00
$127.00
Standard No: GB/T 39300-2020
Document status: VALID
Title in English: Treatment and disposal method for chromium-containing electroplating sludge
Title in Chinese: 含铬电镀污泥处理处置方法
Language: English
File Format: Electronic (PDF)
Delivery: Via email within 1~3 business days
Issued on: 2020-11-19
Implemented on: 2021-10-01
ICS Classification: 13.030.20-Liquid wastes. Sludge
Chinese Classification: Z05-Specifications for pollution control
Professional Classification: GB-National Standard
Related Keywords: chromium content blast furnace method
sintering-blast furnace metallurgy method
sintering-blast furnace metallurgy method roasting
disposal method
method using
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gb/t 39300-2020

《GB/T 39300-2020含铬电镀污泥处理处置方法》由TC294(全国废弃化学品处置标准化技术委员会)归口,主管部门为中国石油和化学工业联合会。


Introduction

Analysis of standard technical framework

This standard innovatively proposes two technical paths: sintering-blast furnace metallurgy method and roasting and leaching method, covering the resource recovery treatment of electroplating sludge with chromium content ≥ 0.4%. Core indicator comparison:

Technical parameters Sintering-blast furnace metallurgy method Roasting and leaching method
Applicable chromium content ≥0.4% Full content range
End products Chromium-containing pig iron/alloy Sodium dichromate
Core temperature range 1700-2000℃ 1150-1200℃
Resource utilization rate Comprehensive recovery rate of iron and chromium>92% Chromium conversion rate>85%

Detailed explanation of sintering - blast furnace metallurgy technology

This technology achieves deep reduction of heavy metals through three-stage temperature control:

  • Drying process: 700-850℃ to evaporate water
  • Sintering process: 1350℃ to form sintered ore
  • Blast furnace smelting: 2000℃ to separate iron and chromium
Key control points: pellet size 8-12mm, bursting temperature ≥380℃, basicity ratio 1.2-1.8.


Technological innovation of roasting and leaching method

Using chromite co-treatment technology, electroplating sludge and chromite are mixed and roasted in a ratio of (0-15):100. Typical case:

A company adopts a rotary kiln-wet grinding combined process to increase the trivalent chromium oxidation efficiency by 40%, and all the mirabilite waste residue is used for sodium sulfide production, achieving zero wastewater discharge.

Key points for environmental protection compliance

According to the requirements of GB18597, the following must be met:

  1. Dust emission concentration ≤30mg/m³
  2. Total chromium content in wastewater ≤1.5mg/L
  3. Establish a full life cycle ledger (storage period ≥5 years)

Implementation suggestions

Enterprises should consider the following when choosing a technical route:

  • For chromium content <1%, roasting method is preferred
  • Blast furnace method that can be integrated with steel production capacity
  • Establish an online monitoring system to monitor dioxin emissions

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