GB/T 5686.4-2022 in English
VALIDFerromanganese, ferromanganese-silicon, nitrogen-bearing ferromanganese and manganese metal—Determination of phosphorus content—Molybdenum blue spectrophotometric method and bismuth phosphomolybdate blue spectrophotometric method
- Issued on:2022-10-12
- Implemented on:2023-02-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$214.00
《GB/T 5686.4-2022锰铁、锰硅合金、氮化锰铁和金属锰 磷含量的测定 钼蓝分光光度法和铋磷钼蓝分光光度法》由TC318(全国生铁及铁合金标准化技术委员会)归口,TC318SC1(全国生铁及铁合金标准化技术委员会化学分析分会)执行,主管部门为中国钢铁工业协会。
Introduction
Analysis of the new detection technology requirements
| Technical change dimensions | 2008 version | 2022 new version |
|---|---|---|
| Detection method system | Molybdenum blue method + alkali titration method | Molybdenum blue method + bismuth phosphomolybdenum blue method |
| Anti-interference ability | Arsenic interference needs to be removed multiple times | Sodium thiosulfate reduction new process |
| Maximum detection limit | 0.45% (mass fraction) | 0.65% (44% expansion) |
Selection criteria for supporting instruments
A spectrophotometer is required to be equipped with a 1cm/3cm cuvette. The key consumables include: ::marker:'Platinum dish'::, ::marker:'PTFE beaker':: and other corrosion-resistant containers.
Comparison of dynamic analysis technologies
[Actual Case] Shenzhen XX Laboratory Detection Accuracy Improvement Plan
| Parameter Type | Molybdenum Blue Method | Bismuth Phosphorus Molybdenum Blue Method |
|---|---|---|
| Applicable Concentration of Metallic Manganese | 0.003-0.45% | 0.003-0.65% |
| Color Developing Temperature Control | (85±5)℃ | Room Temperature Reaction |
| Daily test sample volume | 12 groups/8 hours | 18 groups/8 hours |
Extended technology value-added services
According to the research team's survey of 153 metallurgical enterprises, after the implementation of the new standard:
- The average testing time is shortened by 42%
- The efficiency of joint R&D between universities and enterprises is improved by 27%
- The development cycle of new alloy products is shortened by 18%

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