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thermal desorption ambient air determination sorbent adsorption gas chromatography introduction background secondary desorption technology core method principle sampling voltage change rate resistant parts rice tillering
HJ 583-2010 in English

HJ 583-2010 in English

VALID

Ambient air—Determination of benzene and its analogies using sorbent adsorption thermal desorption and Gas Chromatography

  • Issued on:2010-09-20
  • Implemented on:2010-12-01
  • File Format:PDF
  • Delivery:Via email within 1~3 business days
Price(USD): $150.00
$146.00
Standard No: HJ 583-2010
Document status: VALID
Title in English: Ambient air—Determination of benzene and its analogies using sorbent adsorption thermal desorption and Gas Chromatography
Title in Chinese: 环境空气 苯系物的测定 固体吸附/热脱附-气相色谱法
Language: English
File Format: Electronic (PDF)
Delivery: Via email within 1~3 business days
Issued on: 2010-09-20
Implemented on: 2010-12-01
Superseding: GB/T 14677-1993 Air quality. Determination of toluene, dimethyl benzene and styrene. Gas chromatography
Professional Classification: HJ-Environment
Related Keywords: thermal desorption
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本标准规定了测定空气中苯系物的固体吸附/热脱附-气相色谱法。
本标准适用于环境空气及室内空气中苯、甲苯、乙苯、邻二甲苯、间二甲苯、对二甲苯、异丙苯和苯乙烯的测定。本标准也适用于常温下低浓度废气中苯系物的测定。


Introduction

Background of Standard Revision and Technological Evolution

This standard replaces GB/T 14677-93. The main technical upgrades include:

Revision dimensions1993 edition2010 edition
Detection components5 types8 types (newly added ethylbenzene, isopropylbenzene, etc.)
Standard solution matrixCarbon disulfideMethanol
Chromatographic technologyPacking column onlyAdded capillary column secondary desorption technology

Core method principle

Sampling was performed at room temperature using Tenax adsorption tubes, and the benzene series were desorbed using a thermal desorber (250°C), followed by separation and detection using a gas chromatography-FID system. Critical control points:

  • Aging of sampling tube: 350℃ nitrogen for 120 minutes
  • Safe sampling volume: 6.2L benzene/38L toluene (at 20℃)
  • Storage conditions: 4℃ light-proof and sealed for ≤30 days

Instrument configuration requirements

Typical equipment combination plan

Thermal desorberTemperature range 40-300℃, with secondary cold trap focusing
Gas chromatographFID detector, recommended capillary column: PEG-20M (30m×0.32mm×1.0μm)
Sampling deviceOil-free pump with flow range of 0.01-0.5L/min

Key indicators of quality control

ParametersRequirements
Parallel sample deviation<25%
Recovery rate of the second sampling tube<20%
Intermediate concentration calibrationRelative error≤20%
Detection limit (capillary column)Benzene: 5.0×10-4 mg/m3

Implementation suggestions

  1. Give priority to the capillary column solution to improve the separation of p-xylene/m-xylene
  2. Regularly verify the adsorption efficiency of the Tenax tube, and replace the adsorbent when the recovery rate of the second sampling tube is >15%
  3. For indoor air monitoring, it is recommended to control the sampling flow rate at 50-100ml/min

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