GB/T 13747.26-2022 in English
VALIDMethods for chemical analysis of zirconium and zirconium alloys—Part 26:Determination of alloying and impurity elements content—Inductively coupled plasma atomic emission spectrometry
- Issued on:2022-12-30
- Implemented on:2023-04-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$243.00
《GB/T 13747.26-2022锆及锆合金化学分析方法 第26部分:合金及杂质元素的测定 电感耦合等离子体原子发射光谱法》由TC243(全国有色金属标准化技术委员会)归口,TC243SC3(全国有色金属标准化技术委员会稀有金属分会)执行,主管部门为中国有色金属工业协会。
Introduction
1. Standard Overview
GB/T13747.26-2022 "Chemical Analysis Methods for Zirconium and Zirconium Alloys Part 26: Determination of Alloys and Impurity Elements Inductively Coupled Plasma Atomic Emission Spectrometry" specifies the specific method for determining various alloys and impurity elements in zirconium and zirconium alloys using ICP-AES technology. This standard is applicable to sponge zirconium, zirconium and zirconium alloys, covering element detection from trace to high amounts.
2. Background of Standard Formulation
Zirconium and zirconium alloys have important applications in nuclear power, aerospace and other fields due to their excellent corrosion resistance and low thermal neutron absorption cross-section. With the industry's increasing requirements for material performance, the need for accurate determination of alloying elements and impurity elements is becoming increasingly urgent. This standard provides a standardized operating procedure based on the advantages of ICP-AES technology (such as high sensitivity and simultaneous detection of multiple elements).
3. Comparison of Standard Frameworks
| Standard Part | Determination Elements | Detection Method | Scope of Application |
|---|---|---|---|
| Part 1 | Tin Content | Potassium Iodate Titration and Spectrophotometry | Zirconium Sponge |
| Part 2 | Iron Content | 1,10-Phenanthroline Spectrophotometry and ICP-AES | Zirconium Alloys |
| Part 26 | Various Alloys and Impurity Elements | Inductively coupled plasma atomic emission spectrometry | Zirconium and zirconium alloys |
4. Recommendations for the implementation of the standard
4.1 Laboratory conditions
- Inductively coupled plasma atomic emission spectrometer (ICP-AES)
- Equipped with hydrofluoric acid resistant injection system
- The laboratory should be well ventilated and equipped with radiation protection measures
4.2 Key points for sample preparation
The sample should be processed into chips with a thickness of no more than 5mm. The dissolution process should use high-grade pure reagents, and the acid concentration and heating temperature should be strictly controlled to avoid element loss.
4.3 Notes on data processing
- Ensure that the linear correlation coefficient r≥0.999 when drawing the working curve
- The number of parallel tests shall be no less than two and the average value shall be taken
- Numerical rounding shall be carried out in accordance with GB/T8170

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