GB/T 38229-2019 in English
VALIDTest method for hazard classification of tricresyl phosphate
- Issued on:2019-10-18
- Implemented on:2020-05-01
- File Format:PDF
- Delivery:Via email within 1~3 business days
$156.00
《GB/T 38229-2019磷酸三甲苯酯危险特性分类方法》由TC251(全国危险化学品管理标准化技术委员会)归口,主管部门为国家标准化管理委员会。
Introduction
Overview of Classification Methods for Hazardous Properties of Tricresyl Phosphate
Tricresyl Phosphate is an important chemical raw material, widely used in flame retardant plasticizers for plastics and rubber, as well as in the paint industry. Due to its toxicity, correct classification and transportation are essential.
Background of Standard Formulation
The United Nations "Recommendations on the Transport of Dangerous Goods Model Regulations" lists tricresyl phosphate as a toxic substance under Category 6.1 (UN No. 2574), but it only applies to cases where the content of the ortho-isomer exceeds 3%. Therefore, the accurate determination of the content of tri-ortho-cresyl phosphate (TONP) in tricresyl phosphate is the key to classification.
Experimental methods and technical requirements
| Project | Reagents and materials | Instruments and equipment | Determination conditions |
|---|---|---|---|
| Sample treatment | Ethyl acetate (chromatographic grade), tri-o-cresyl phosphate standard (≥99%). | Gas chromatography-mass spectrometry (GC-MS), organic filter membrane (0.22μm), analytical balance (accurate to 0.1mg). | Chromatographic column: HP-5MS 30m×0.25mm, capillary column; column temperature was initially 100°C, increased to 220°C at 30°C/min, and then increased to 300°C at 15°C/min, and maintained for 5 minutes. |
| Quantitative analysis | Standard stock solution (100mg/L) and standard working solution (concentration range: 0.1mg/L to 10.0mg/L). | - Injection volume: 1μL - Gas flow rate: 1mL/min - Splitless injection | The mass spectrometer scanning mode was selected ion monitoring (SIM) mode, and the qualitative and quantitative ions are shown in Table 1. |
Comparative Analysis of Standard Frameworks
The classification of hazardous properties of tricresyl phosphate is different according to international and domestic standards:
1. Comparison of international and domestic transportation rules
| Classification Basis | United Nations TDG | International Ocean Shipping IMDG | Air Transport ICAO-TI |
|---|---|---|---|
| Hazard Classification | 6.1 Toxic Substances | Class 6 Toxic Goods | Class 6 Toxic Goods |
| Transport Conditions | UN number 2574 applies to tricresyl phosphate with TONP content ≥3%. | The same classification criteria apply. | Expert judgment is required on physical, chemical and toxicological data. |
Implementation recommendations
To ensure the correct classification and transportation of tricresyl phosphate, it is recommended to:
- Sample testing: Use GC-MS to determine the TONP content to ensure the accuracy of the test.
- Result analysis: According to the standard (GB/T38229-2019), when TONP ≥3%, it is classified as a 6.1 toxic substance; otherwise, it is necessary to combine physical and chemical data and expert judgment.
- Transportation labeling: Correctly mark the hazard category and choose packaging and transportation methods that meet international standards.
- Compliance Checks: Regularly review test methods and classification basis to ensure compliance with the latest regulatory requirements.

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