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Fluorescence Quantitative Analysis Methods

Fluorescence Quantitative Analysis Methods, Total:173 items.

The international standard classification for "Fluorescence Quantitative Analysis Methods" includes: Cadmium, cobalt and their alloys , Other non-ferrous metals and their alloys , Metalliferous minerals , Chemical analysis , Lead, zinc, tin and their alloys , Chemical analysis of metals , Aluminium and aluminium alloys , Materials for aluminium production , Copper and copper alloys , Non-ferrous metals in general , Corrosion of metals , Non-ferrous metals , Non-metalliferous minerals , Salts , Ambient atmospheres , Aluminium , Other iron and steel products .

The Chinese standard classification for "Fluorescence Quantitative Analysis Methods" includes: Heavy metals and their alloys analysis method , Rare metals and their alloys analysis method , Light metals and their alloys analysis method , Heavy metal ore , Metallurgy material and auxiliary material in general , Semimetal and semiconductor material analysis method , Metal physical property test method , Carbon material , Light metals and their alloys , Light metal ore , Rare refractory metals and their compounds , Rare metal ore , Oxide and elementary substance , Rare scattered metals and their alloys , Precious metals and its alloy analysis method , Building material raw material ore , Precious metal ore , Analysis and test methods for radioactive substances and radiation intensity , Other non-metal ore , Beneficiation reagent .


国家能源局

  • SY/T 7309-2016 Quantitative fluorescence techniques for reservoir analysis

Professional Standard - Non-ferrous Metal

  • YS/T 74.1-2010 Methods for chemical analysis of cadmium—Part 1:Determination of arsenic content—Hydride generation-atomic fluorescence spectrometry
  • YS/T 581.10-2006 Determination of chemical contents and physical properties of aluminium fluoride Part 10: Determination of sulphur content by X-ray fluorescence spectrometric method
  • YS/T 872-2023 Methods for chemical analysis of gallium—— Determination of mercury and arsenic—— Atomic fluorescence spectrometer analytical method
  • YS/T 581.18-2012 Chemical analysis methods and physical properties of Aluminum Fluoride—Part 18:X-ray fluorescence spectrometric method for the determination of elements content using pressed powder tablets
  • YS/T 703-2014 Method for chemical analysis of Limstone―Determination of element contents―X-ray fluorescence spectrometric method
  • YS/T 1075.8-2015 Methods for chemical analysis of vanadium-aluminium and molybdenum-aluminium master alloys―Part 8:Determination of molybdenum and aluminium contents―X-ray fluorescence method
  • YS/T 472.3-2005 Methods for chemical analysis of nickel concentrates and cobalt sulfide concentrates --Determination of mercury content -- Hydride generation-atomic fluorescence spectrometry
  • YS/T 536.7-2009 Methods for chemical analysis of bismuth—Determination of arsenic content—Atomic fluorescence spectrometric method
  • YS/T 521.3-2009 Methods for chemical analysis of blister copper—Part 3:Determination of arsenic content—Hydride generation-atomic fluorescence spectrometric method—Potassium bromate titration
  • YS/T 461.6-2003 The methods of chemical analysis of lead and zine bulk concentrates - The determination of mercury content - The atomic fluorescence spectrometry method
  • YS/T 276.2-2011 Methods for chemical analysis of indium Part 2:Determination of tin content-Phenylfluorone-cetyltrimethyl ammonium bromide spectrophotometry
  • YS/T 227.1-2010 Methods for chemical analysis of tellurium - Part 1: Determination of bismuth content - Hydride generation-atomic fluorescence spectrometry
  • YS/T 872-2013 Methods for chemical analysis gallium—Determination of mercury in industrial gallium—Atomic fluorescence spectrometer method
  • YS/T 520.9-2006 Methods for chemical analysis of gallium. The phenylfluorone-polyethylene glycol octyl phenyl ether photometric method for the determination of germanium content
  • YS/T 248.2-2007 Methods for chemical analysis of crude lead - Determination of tin content-Phenylfuorone photometric method and potassium iodate titrimetric method
  • YS/T 556.6-2009 Methods for chemical analysis of antimony concentrates—Part 6:Determination of selenium content—Hydride generation-atomic fluorescence spectrometric method
  • YS/T 226.2-2009 Methods for chemical analysis of selenium - Part 2: Determination of antimony content - Hydride generation-atomic fluorescence spectrometry
  • YS/T 74.9-2010 Methods for chemical analysis of cadmium—Part 9:Determination of tin content—Hydride generation-atomic fluorescence spectrometry
  • YS/T 229.2-2013 Methods for Chemical Analysis of High Pure Lead - Part 2: Determination of Arsenic Content - Atomic Fluorescence Spectrometry
  • YS/T 229.3-2013 Methods for Chemical Analysis of High Pure Lead - Part 3: Determination of Antimony Content - Atomic Fluorescence Spectrometry
  • YS/T 536.11-2009 Method for chemical analysis of bismuth - Determination of mercury content - Atomic fluorescence spectrometric method
  • YS/T 555.4-2009 Methods for chemical analysis of molybdenum concentrate—Determination of tin content—Atomic fluorescence spectrometry
  • YS/T 276.1-2011 Methods for chemical analysis of indium Part 1:Determination of arsenic content -Hydride generation-atomic fluorescence spectrometry
  • YS/T 575.23-2009 Method for chemical analysis of aluminum ores—Part 23:Determination of element contents X-ray fluorescence spectrometric method
  • YS/T 1605.5-2023 Methods for chemical analysis of roasted molybdenum concentrate— Part 5: Determination of antimony content— Atomic fluorescence spectrometry
  • YS/T 273.15-2012 Chemical analysis methods and physical properties of cryolite—Part 15:X-ray fluorescence spectrometric method for the determination of elements content using pressed powder tablets
  • YS/T 739.1-2023 Chemical analysis methods of aluminium electrolyte- Part 1: Determination of elements content – X-ray fluorescence spectrometry method
  • YS/T 1605.4-2023 Methods for chemical analysis of roasted molybdenum concentrate— Part 4: Determination of tin content— Atomic fluorescence spectrometry
  • YS/T 273.14-2008 Chemical analysis methods and determination of physical performance of synthetic cryolity Part 14:X-ray fluorescence spectrometric method for the determination of elements content
  • YS/T 555.3-2009 Methods for chemical analysis of molybdenum concentrate—Determination of arsenic content—Atomic fluorescence spectrometry
  • YS/T 745.8-2010 Methods for chemical analysis of copper anode slime - Part 8: Determination of arsenic content - Hydride generation-atomic fluorescence spectrometry method
  • YS/T 74.2-2010 Methods for chemical analysis of cadmium—Part 2:Determination of antimony content—Hydride generation-atomic fluorescence spectrometry
  • YS/T 556.7-2009 Methods for chemical analysis of antimony concentrates—Part 7:Determination of mercury content—Atomic fluorescence spectrometry
  • YS/T 710.4-2009 Method for chemical analysis of cobalt oxide—Part 4:Determination of arsenic content—Atomic fluorescence spectrometry
  • YS/T 281.15-2011 Methods for chemical analysis of cobalt- Part 15:Determination of arsenic antimony and bismuth content-Hydride generation-atomic fluorescence spectrometery
  • YS/T 746.15-2010 Methods for chemical analysis of lead-free tin-based solders - Part 15: Determination of Germanium content - Salicylfluorone-sim polyethylene glycol phenyl ether spectrophotometry
  • YS/T 273.11-2006 Chemical analysis methods and physical properties of cryolite - Part 11: Determination of sulphur content by X-ray fluorescence spectrometric method
  • YS/T 472.5-2005 Methods for chemical analysis of nickel concentrates and cobalt sulfide concentrates --Determination of arsenic content -- Hydride generation-atomic fluorescence spectrometry
  • YS/T 581.16-2008 Chemical analysis methods and determination of physical performance of industrial aluminium fluoride Part 16:X-ray fluorescence spectrometric method for the determination of elements
  • YS/T 227.10-2010 Methods for chemical analysis of tellurium - Part 10: Determination of arsenic content - Hydride generation-atomic fluorescence spectrometry
  • YS/T 273.11-2023 Methods for chemical analysis and physical properties test of cryolite— Part 11: Determination of elements content— X-ray fluorescence spectrometric method
  • YS/T 1617.2-2023 Methods for chemical analysis of indium oxide— Part 2:Determination of arsenic content— Atomic fluorescence spectrometry
  • YS/T 63.16-2006 Carbonaceous materials used in the production of aluminium?Part 16:Analysis using an X-ray fluorescence method
  • YS/T 226.1-2009 Methods for chemical analysis of selenium - Part 1: Determination of bismuth content - Hydride generation-atomic fluorescence spectrometry
  • YS/T 461.6-2013 Methods for Chemical Analysis of Lead and Zinc Bulk Concentrates - Part 6: The Determination of Mercury Content - The Atomic Fluorescence Spectrometry

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China

  • GB/T 3884.10-2012 Methods for chemical analysis of copper concentrstes - Part 10: Determination of Antimony content - Hydride generation atomic fluorescence spectrometry method
  • GB/T 4325.4-2013 Methods for chemical analysis of molybdenum—Part 4:Determination of tin content—Atomic fluorescence spectrometry
  • GB/T 8152.11-2006 Methods for chemical analysis of lead concentrates - Determination of mercury content - Atomic fluorescence spectrometer method
  • GB/T 14506.28-1993 Silicate rocks. Determination of contents of major and minor elements. X-ray fluorescence spectrometric method
  • GB/T 12378-1990 Analytical method of microquantity uranium in air by spectrophotofluoremetry after extraction with TBP
  • GB/T 8156.10-1987 Aluminium fluoride for industrial use--Determination of sulphur content--X-ray fluorescence spectrometric method
  • GB/T 14849.5-2014 Methods for chemical analysis of silicon metal―Part 5:Determination of impurity contents―X-ray fluorescence method
  • GB/T 4325.5-2013 Methods for chemical analysis of molybdenum—Part 5:Determination of antimony content—Atomic fluorescence spectrometry
  • GB/T 4325.3-1984 Methods for chemical analysis of molybdenum;The polyethylene glycol octyl phenyl ether-phenyl fluorine photometric method for the determination of tin content
  • GB/T 12689.2-2004 The methods for chemical analysis of zinc and zinc alloys—The determination of arsenic content—The atomic fluorescence spectrometer method
  • GB/T 14849.5-2010 Chemical analysis of slion metal—Part 5:Determination of elements content—Analysis using an X-ray fluorescence method
  • GB/T 6150.13-2022 Methods for chemical analysis of tungsten concentrates—Part 13:Determination of arsenic content—Atomic fluorescence spectrometry and the silver diethyldithiocarbamate(DDTC-Ag)spectrophotometry
  • GB/T 23273.3-2009 Methods for chemical analysis of cobalt oxatate - Part 3: Determination of arsenic content - Hydride generation-atomic fluorescence spectrometry
  • GB/T 14849.10-2016 Methods for chemical analysis of industrial silicon - Part 10: Determination of mercury content - Atomic fluorescence spectrometric method
  • GB/T 3253.10-2009 Methods for chemical analysis of antimony and antimony trioxide—Determination of mercury content—Atomic fluorescence spectrometric method
  • GB/T 17416.2-1998 Method for chemical analysis of Zirconium ores-Determination of Zirconium and Hafnium contents-X-ray fluorescence spectrometric method
  • GB/T 4325.6-2013 Methods for chemical analysis of molybdenum—Part 6:Determination of arsenic content—Atomic fluorescence spectrometry
  • GB/T 6609.30-2009 Chemical analysis methods and determination of physical performance of alumina - Part 30: X-ray fluorescence spectrometric method for the determination centent of trace elements
  • GB/T 8151.11-2012 Methods for chemical analysis of zinc concentrates—Part 11:Determination of antimony content—Hydride generation-atomic fluorescence spectrometry
  • GB/T 7731.7-1987 Methods for chemical analysis of ferrotungsten--The phenylfluorone photometric method for the determination of tin content
  • GB/T 20899.12-2016 Methods for chemical analysis of gold ores - Part 12: Determination of arsenic, mercury, cadmium, lead and bismuth atomic fluorescence spectrometric method
  • GB/T 23362.1-2009 Methods for chemical analysis of high purity indium hydroxide - Part 1: Determination of arsenic content - Atomic fluorescence spectrometry
  • GB/T 8151.10-2012 Methods for chemical analysis of zinc concentrates—Part 10:Determination of tin content—Hydride generation-atomic fluorescence spectrometry
  • GB/T 8152.5-2006 Methods for chemical analysis of lead concentrates - Determination of arsenic content - Atomic fluorescence spectrometer method
  • GB/T 3253.6-2008 Methods for chemical analysis of antimony and antimony trioxide - Determination of selenium content - Atomic fluorescence spectrometer method
  • GB/T 11066.9-2009 Methods for chemical analysis of gold—Determination of arsenic and tin contents—Hydride generation-atomic fluorescence spectrometry
  • GB/T 12377-1990 Analytical method of microquantity uranium in air by laser-fluoremetry
  • GB/T 23364.3-2009 Methods for chemical analysis of high purity indium oxide - Part 3: Determination of antimony content - Atomic fluorescence spectrometry
  • GB/T 8151.15-2005 Methods for chemical analysis of zinc concentrates-Determination of mercury content-Atomic fluorescence spectrometry method
  • GB/T 4324.3-1984 Methods for chemical analysis of tungsten - The polyethylene glycol octyl phenyl ether-phenylfluorone photometric method for the determination of tin content
  • GB/T 18116.3-2000 Yttrium-europium oxide-Determination of europium oxide content-Fluorescent spectrophotometric method
  • GB/T 23113-2008 Measurement of mercury level in fluorescent lamps
  • GB/T 3253.7-2009 Methods for chemical analysis of antimony and antimony trioxide—Determination of bismuth content—Atomic fluorescence spectrometric method
  • GB/T 7739.12-2016 Methods for chemical analysis of gold concentrates - Part 12: Determination of arsenic, mercury, cadmium, lead and bismuth atomic fluorescence spectrometric method
  • GB/T 12689.9-2004 The methods for chemical analysis of zinc and zinc alloys—The determination of antimony content—The atomic fluorescence spectrometer and the flame atomic absorption spectrometric met
  • GB/T 23362.2-2009 Methods for chemical analysis of high purity indium hydroxide - Part 2: Determination of tin content - Phenylfluorone spectrophotometry
  • GB/T 23364.1-2009 Methods for chemical analysis of high purity indium oxide - Part 1: Determination of arsenic content - Atomic fluorescence spectrometry
  • GB/T 23364.2-2009 Methods for chemical analysis of high purity indium oxide - Part 2: Determination of tin content - Phenylfluorone spectrophotometry
  • GB/T 6150.17-2022 Methods for chemical analysis of tungsten concentrates—Part 17:Determination of antimony content—Atomic fluorescence spectrometry
  • GB/T 6987.10-2001 Aluminium and aluminium alloys-Determination of copper content-Phenyl fluorone spectrophotometric method
  • GB/T 23362.3-2009 Methods for chemical analysis of high purity indium hydroxide - Part 3: Determination of antimony content - Atomic fluorescence spectrometry
  • GB/T 4325.3-2013 Methods for chemical analysis of molybdenum - Part 3: Determination of bismuth content - Atomic fluorescence spectrometry

中华人民共和国环境保护部

  • GB 12377-1990 Analytical method of microquantity uranium in air by laser-fluoremetry and spectropho to fluoremetry after extraction with TBP
  • GB 12378-1990 Analytical method of microquantity uranium in air by spectropho to fluoremetry after extraction with TBP

Professional Standard - Nuclear Industry

  • EJ/T 823-1994 Laser fluorescence trace uranium analyzer
  • EJ 296.2-1987 Analytical method of trace uranium in urine laser liquid fluorescence method
  • EJ/T 823-2016 Trace uranium fluorescence analyzer
  • EJ/T 296.1-1987 Analytical method of trace uranium in urine solid fluorescence method

Professional Standard - Geology

  • DZ/T 0064.38-2021 Methods for analysis of groundwater quality- Part 38: Determination of selenium content- Hydride generation-atomic fluorescence spectrophotometry
  • DZ/T 0064.81-2021 Methods for analysis of groundwater quality- Part 81: Determination of mercury content- Atomic fluorescence spectrometry
  • DZ/T 0064.11-2021 Methods for analysis of groundwater quality- Part 11: Determination of arsenic content- Hydride generation atomic fluorescence spectrometry

工业和信息化部

  • YS/T 1341.6-2019 Methods for chemical analysis of crude zinc - Part 6: Determination of arsenic content - Atomic fluorescence spectrometry
  • YS/T 1033-2015 Determination of element contents in dry barrier―X-ray fluorescence spectrometric method
  • YS/T 1171.8-2017 Methods for chemical analysis of regenerated zinc material一Part 8:Determination of mercury content-Atomic fluorescence spectrometry and cold atomic absorption spectrometric method
  • YS/T 1341.8-2019 Methods for chemical analysis of crude zinc - Part 8: Determination of tin content - Atomic fluorescence spectrometry
  • YS/T 1171.7-2017 Methods for chemical analysis of regenerated zinc material一Part 7:Determination of arsenic and antimony contents-Atomic fluorescence spectrophotometry
  • YS/T 1288.3-2018 Methods for chemical analysis of high purity zinc- Part 3:Determination of arsenic content-Hydride generation-atomic fluorescence spectrometry
  • YS/T 445.13-2019 Methods for chemical analysis of silver concentrates - Part 13: Determination of mercury content Atomic fluorescence spectrometry
  • YS/T 806-2020 Method for chemical analysis of aluminium and aluminium alloys-Determination of element contents-X-ray fluorescence spectrometry
  • YS/T 1381-2020 Method for chemical analysis of rhodium compounds. Determination of arsenic content. Atomic fluorescence spectrometry
  • YS/T 581.15-2012 Methods for chemical analysis and determination of physical properties of aluminum fluoride Part 15: Determination of elemental content by X-ray fluorescence spectrometry (tablet pressing) method
  • YS/T 575.23-2021 Methods for chemical analysis of bauxite-Part 22:Determination of hydroscopic moisture-Gravimetric method
  • YS/T 1341.7-2019 Methods for chemical analysis of crude zinc - Part 7: Determination of antimony content - Atomic fluorescence spectrometry

海关总署

  • HS/T 52-2016 X-ray fluorescence quantitative analysis method for magnesium oxide series mineral products

Professional Standard - Education

中华人民共和国国家质量监督检验检疫总局、中国国家标准化管理委员会

  • GB/T 1819.17-2017 Methods for chemical analysis of tin concentrates - Part 17: Determination of mercury content - Atomic fluorescence spectrometric method

Professional Standard - Aviation

  • HB 5218.20-1995 Aluminum Alloy Chemical Analysis Method: Phenylfluorone Photometric Determination of Tin Content
  • HB/Z 5218.20-2004 Methods for chemical analysis of aluminium alloys-Part 20:Determination of tin content by phenyl fluorone spectrophotometric method

Shandong Provincial Standard of the People's Republic of China

  • DB37/T 266-1999 X-ray fluorescence analysis method for the determination of the amount of waste slag added in building material products

Professional Standard - Ferrous Metallurgy

  • YB/T 5044-1993 Chemical analysis of lump molybdenum oxide The determination of tin by the photometric method of phenylfluorone
  • YB/T 4177-2008 Determination of chemical composition in slag by X-ray fluorescence spectrometry

Professional Standard - Commodity Inspection

  • SN/T 2297.7-2015 Analysis method for gypsum and gysum products―Part 7:Determination of arsenic and mercury content―Atomic fluorescence spectrum

Guangdong Provincial Standard of the People's Republic of China

  • DB44/T 1602-2015 Analysis Method of Stone Composition--X-ray Fluorescence Spectrometry

Professional Standard - Rare Earth

  • XB/T 610.1-2007 Chemical analysis methods for samarium cobalt permanent magnet alloy powder Determination of samarium and cobalt X-ray fluorescence spectrometric method

Professional Standard - Agriculture

Japanese Industrial Standards Committee (JISC)

Association Francaise de Normalisation

  • NF A06-358:1985 Chemical analysis of steel and cast iron. Determination of cerium content. Fluorimetric and amperometric method.
  • NF M07-095*NF EN ISO 14597:1999 Petroleum products. Determination of vanadium and nickel content. Wavelength-dispersive X-ray fluorescence spectrometry.

Korean Agency for Technology and Standards (KATS)

  • KS J 4207-2011 Spectrophotometric and fluorometric analysis methods for GMO quantification
  • KS D 1655-1993 Method for X-Ray Fluorescence Spectrometric Analysis of Iron and Steel
  • KS E 3045-2002 X--ray fluorescence spectrometric analysis for iron ores
  • KS D 1655-2008(2019) Method for X-ray fluorescence spectrometric analysis of iron and steel
  • KS D 1686-2011(2016) Method for x-ray fluorescence spectrometric analysis of ferroalloys
  • KS J 4207-2011(2021) Spectrophotometric and fluorometric methods for GMO quantification
  • KS D 1655-2019 Method for X-ray fluorescence spectrometric analysis of iron and steel
  • KS L 5222-2009 Chemical analysis method of cement by x-ray fluorescence
  • KS D 1686-2011(2021) Method for x-ray fluorescence spectrometric analysis of ferroalloys
  • KS D 1686-2021 Method for x-ray fluorescence spectrometric analysis of ferroalloys
  • KS D 2597-1996(2016) Method for X-ray fluorescence spectrometric analysis of zirconium and zirconium alloys
  • KS M 1068-2005 Qualitative/quantitative screening by XRF spectrometry
  • KS D 1898-1993 Method for fluorescent X-ray analysis of copper alloys
  • KS M 0026-2013 General rules for fluorometric analysis
  • KS D 2597-1996(2021) Method for X-ray fluorescence spectrometric analysis of zirconium and zirconium alloys
  • KS E 3076-2017 Methods for X-ray fluorescence spectrometric analysis of silica stone and silica sand
  • KS E 3076-2022 Methods for X-ray fluorescence spectrometric analysis of silica stone and silica sand
  • KS M 0026-2008 General rules for fluorometric analysis
  • KS L 3316-1988 Method for X-ray fluorescence spectrometric analysis of refractory products
  • KS L 3316-1998 Method for X-ray fluorescence spectrometric analysis of refractory products
  • KS D 2710-2008 Methods for X-ray fluorescence spectrometric analysis of ferroniobium
  • KS L 3316-2014(2019) Method for X-ray fluorescence spectrometric analysis of refractory products
  • KS D 2597-2021 Method for X-ray fluorescence spectrometric analysis of zirconium and zirconium alloys
  • KS E 3075-2002 Method for X-ray fluorescence spectrometric analysis of limestone and dolomite
  • KS L 3316-2014 Method for X-ray fluorescence spectrometric analysis of refractory products
  • KS L 3316-2019 Method for X-ray fluorescence spectrometric analysis of refractory products

KR-KS

Australian/New Zealand Standard (AU-AS/NZS)

  • AS/NZS 4782.3(Int):2006 Double-capped fluorescent lamps - Performance specifications - Procedure for quantitative analysis of mercury present in fluorescent lamps
  • AS/NZS 1050.24:1994(R2016) Methods for the analysis of iron and steel - Determination of aluminium content (spectrophotometric method)
  • AS/NZS 1050.8:1994(R2016) Methods for the analysis of iron and steel - Determination of manganese content (spectrophotometric method)
  • AS/NZS 1050.27:1994(R2016) Methods for the analysis of iron and steel - Determination of titanium content (spectrophotometric method)
  • AS/NZS 4782.3:2006 Double-capped fluorescent lamps— Performance specifications Part 3: Procedure for quantitative analysis of mercury present in fluorescent lamps
  • AS/NZS 4782.3:2014 Double-capped fluorescent lamps — Performance specifications, Part 3: Procedure for quantitative analysis of mercury present in fluorescent lamps
  • AS/NZS 1050.21:1994 Methods for the analysis of iron and steel - Determination of cobalt content (spectrophotometric method)
  • AS/NZS 1050.21:1994(R2016) Methods for the analysis of iron and steel - Determination of cobalt content (spectrophotometric method)
  • AS/NZS 1050.24:1994 Methods for the analysis of iron and steel - Determination of aluminium content (spectrophotometric method)
  • AS/NZS 1050.8:1994 Methods for the analysis of iron and steel - Determination of manganese content (spectrophotometric method)
  • AS/NZS 1050.27:1994 Methods for the analysis of iron and steel - Determination of titanium content (spectrophotometric method)

HU-MSZT

  • MSZ 20992/5-1970 Chemical analysis of ferrosilicon, determination of fluorescent phosphorus content

RO-ASRO

  • STAS 9538/3-1981 PAPER FOR CHROMATOGRAPHY AND ELECTROPHORESIS Fluorescence analysis

IN-BIS

  • IS 12803-1989 Method for analyzing hydraulic cement using X-ray fluorescence spectrometer